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Among the following ions the ppi-dpi ove...

Among the following ions the `ppi-dpi` overlap could be present in

A

`NO _(3) ^(-)`

B

`PO_(4) ^(3-)`

C

`CO_(3) ^(2-)`

D

`NO_(2) ^(-)`

Text Solution

Verified by Experts

The correct Answer is:
B

In `PO_(4)^(30),P` is `sp^(3)-`hybridized It forms four P-O. `sigma-`bond by overlap of `sp^(3)-`orbitals of P with P-orbital of O. The `pi-`bond is, however. Formed overlep of p-orbital of O and d-orbital of P.

N and C, on the other hand , cannot form `pi-dpi` bond since they do not have d-orbitals.
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VMC MODULES ENGLISH-CHEMICAL BONDING & MOLECULAR STRUCTURE -SOLVED EXAMPLES
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  11. Which of the following is paramagnetic ?

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  12. Among LiCl, RbCl, BeCl2, MgCl2, the compounds with greatest and least ...

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  13. Which of the following molecular orbitals has two nodal planes ?

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  14. In PO(4)^(3-) the formal charge on each O-atom and P-O bond order resp...

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  15. Among the following ions the ppi-dpi overlap could be present in

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  16. Which of the following molecules is linear ?

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  17. Which of the following hydride is ionic ?

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  19. How many type of bond lengths are there in SO(3) ^(2-) ?

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