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The interatomic distance in H(2) and CI(...

The interatomic distance in `H_(2)` and `CI_(2)` molecules are 74 an d198 pm respectively. The bond length of HCI is

A

272pm

B

136pm

C

127pm

D

248pm

Text Solution

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The correct Answer is:
To find the bond length of HCl given the interatomic distances of H2 and Cl2, we can follow these steps: ### Step-by-Step Solution: 1. **Understand Interatomic Distance**: The interatomic distance in a diatomic molecule (like H2 or Cl2) is the distance between the centers of the two atoms. For a diatomic molecule, this distance can be expressed as \( d = 2r \), where \( r \) is the atomic radius. 2. **Calculate the Radius of H2**: - The interatomic distance for H2 is given as 74 pm. - Using the formula \( d = 2r \), we can find the radius of H2: \[ r_{H2} = \frac{d_{H2}}{2} = \frac{74 \text{ pm}}{2} = 37 \text{ pm} \] 3. **Calculate the Radius of Cl2**: - The interatomic distance for Cl2 is given as 198 pm. - Similarly, we find the radius of Cl2: \[ r_{Cl2} = \frac{d_{Cl2}}{2} = \frac{198 \text{ pm}}{2} = 99 \text{ pm} \] 4. **Calculate the Bond Length of HCl**: - The bond length of HCl is the sum of the radii of H and Cl: \[ \text{Bond length of HCl} = r_{H2} + r_{Cl2} = 37 \text{ pm} + 99 \text{ pm} = 136 \text{ pm} \] 5. **Final Answer**: The bond length of HCl is 136 pm.
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