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Carbon tetrachloride...

Carbon tetrachloride

A

Its planar struture

B

Its regular tetrahedral structure

C

Similar sizes of carbon and chlorine atoms

D

Similar electron affinities of carbon and chlorine

Text Solution

Verified by Experts

The correct Answer is:
B
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Match the following in column A with the correct answer form the choices given in column B: Column A: 1. Ammonium hydroxide soln., 2. Dilute hydrochloric acid, 3. Carbon tetrachloride Column B: A:Contains only ions, B: Contains only molecules, C: Contains ions & molecules

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Choose A,B,C or D match the descriptions (i) to (iv) alphabets may be repeated . (A) nonelectrolyte (B) strong elestrolyte (C ) weak electrolyte (D) metallic conductor (i) Molten ionic compound (ii) Carbon tetrachloride (iii) An aluminium wire (iv) A solution containing solvent molecules , solute molecules and ions formed by the dissociation of solute molecules . (v) A sugar solution with sugar molecules and water molecules .

Methane is the first member of alkane, when it is treated with excess of chlorine in the presence of diffused sunlight forms carbon tetrachloride. Draw the appropriate structural formula of carbon tetrachloride and state the type of bond present in it.

Compound (A) C_(6)H_(12) gives a positive test with bromine in carbon tetrachloride. Reaction of (A) with alkaline KMnO_(4) yields only (B) which is the potassium salt of an acid. Write structure formulae and IUPAC name of (A) and (B).

Equation for the reaction when compound A is bubbled through bromine dissolved in carbon tetrachloride is as follows: A overset(Br_(2)//C Cl_(4)) to underset(CH_(2)Br)underset(|)(CH_(2))Br Draw the structure of A.

An unknown compound decolorizes bromine in carbon tetrachloride, and it undergoes catalytic reduction to give decalin. When treated with warm, conc, potassium permangate, this compound give cis-cyclohexane-1, 2-dicaboxylic acid and oxalic acid. Possible a structure for th unknown compound is-

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Compond A is bubbled through bromine dissolved in carbon tetrachloride and the product is CH_2Br - CH_2Br . A overset(Br_2//"CC"l_4) rarr CH_2 Br - CH_2 Br . (i) (i) Draw the structural formula of A. (ii) What type of reaction has undergone ? (iii) What is your observation ? (iv) Name (not formula) the compound formed when steam reacts with A in the presence of phosphoric acid. (v) What is the procedure for converting the product of (iv) back to A?

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