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A closed vessel contains equal number of...

A closed vessel contains equal number of nitrogen and oxygen molecules at pressure of `P mm`. If nitrogen is removed from the system, then the pressure will be:

A

P

B

2P

C

`(P)/(2)`

D

`P^(2)`

Text Solution

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The correct Answer is:
To solve the problem, we will follow these steps: ### Step-by-Step Solution: 1. **Understanding the Initial Conditions**: - We have a closed vessel containing equal numbers of nitrogen (N₂) and oxygen (O₂) molecules. - The total pressure in the vessel is given as P mm. 2. **Applying Dalton's Law of Partial Pressures**: - According to Dalton's Law, the total pressure (P) in a mixture of gases is the sum of the partial pressures of each gas. - Therefore, we can express the total pressure as: \[ P = P_{N_2} + P_{O_2} \] 3. **Determining the Partial Pressures**: - Since there are equal numbers of nitrogen and oxygen molecules, the partial pressures will also be equal. - Let \( P_{N_2} = P_{O_2} \). - Thus, we can write: \[ P_{N_2} = P_{O_2} = \frac{P}{2} \] 4. **Removing Nitrogen from the System**: - If nitrogen is removed from the system, only oxygen remains in the vessel. - The pressure of the remaining gas (oxygen) will now be equal to its partial pressure, which we calculated as: \[ P_{O_2} = \frac{P}{2} \] 5. **Final Pressure Calculation**: - Since only oxygen is present after the removal of nitrogen, the final pressure in the vessel will be: \[ P_{final} = P_{O_2} = \frac{P}{2} \] ### Conclusion: The final pressure in the vessel after removing nitrogen will be \( \frac{P}{2} \).
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