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Sulphur exists in more than one solid fo...

Sulphur exists in more than one solid form. The stable form at room temperature is rhombic sulphur. But above room temperature the following reaction occurs :
S (rhombic) `rarr` S (monoclinic)
If `Delta H = 276.144` J at 298 K and 1 atm and `Delta G = 75.312 J`
Assume that `Delta H` and `Delta S` do not vary significantly with temperature, calculate `T_(eq)`, the temperature at which rhombic and monoclinic sulphur exist in equilibrium with each other.

Text Solution

AI Generated Solution

To find the equilibrium temperature \( T_{eq} \) at which rhombic and monoclinic sulfur exist in equilibrium, we can use the Gibbs free energy equation under equilibrium conditions. ### Step-by-step Solution: 1. **Understanding the Gibbs Free Energy Equation**: At equilibrium, the change in Gibbs free energy (\( \Delta G \)) is zero. The relationship between \( \Delta G \), \( \Delta H \) (enthalpy change), and \( \Delta S \) (entropy change) is given by: \[ \Delta G = \Delta H - T \Delta S ...
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Sulphur exists is more than one solid form. The stable form at room temperature is rhombic sulphur. But above room temperature the following reaction occurs. S ("rhomic") rarrS("monoclinic") If DeltaH^(Theta) =- 276.144J at 298 K and 1atm and DeltaG^(Theta) = 75.312J a. Calculate DeltaS^(Theta) at 298K .

Sulphur exists in more than one solid form. The stable form at room temperature is rhombic sulphur. But above room temperature the following reaction occurs. S ("rhombic") rarrS("monoclinic") If DeltaH^(Theta) = 276.144J at 298 K and 1atm and DeltaG^(Theta) = 75.312J a. Calculate DeltaS^(Theta) at 298K . b. Assume that DeltaH^(Theta) and DeltaS^(Theta) do not vary significantly with temperature, calculate T_(eq) , the temperature at which rhombic and monoclinic sulphur exist in equilibrium with each other.

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