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In Cannizzaro reaction given below : ...

In Cannizzaro reaction given below :
` 2PhCHO overset(: OH^(-)) to PhCH_(2)OH + PhCOO^(-)` the slowest step is

A

The attack of `OH^(-)` at the carbonyl group

B

The transfer of hydride to the carbonyl group

C

The abstraction of proton from the carboxylic acid

D

The deprotonation of `Ph-CH_(2)OH`

Text Solution

Verified by Experts

In the Cannizzarro's reaction given below `:`
`2Ph-CHO overset( OH^(-))(rarr) Ph -CH_(2)OH +PhCOO^(-)`
The slowest step is transfer of hydride oin ( refer to the mechanism of Cannizzaro reaction ) to the carbonyl group of second mole of aldehyde . Hence, it is represented in following reaction mechanism.
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VMC MODULES ENGLISH-ALDEHYDES,KETONES & CARBOXYLIC ACIDS -EXAMPLE 1
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