Home
Class 12
CHEMISTRY
Acetone overset( HCN) ( rarr) ( A) overs...

Acetone `overset( HCN) ( rarr) ( A) overset( H_(3) O^(+))(rarr) ( B ) `. In the above sequence of reaction A and B are `:`

A

`( CH_(3))_(2) C( OH ) CN, ( CH_(3))_(2)C( OH ) COOH`

B

`( CH_(3))_(2)C(OH) CN, ( CH_(3))_(2)C ( OH)_(2)`

C

`( CH_(3))_(2)C(OH)CN,(CH_(3))_(2)CHCOOH`

D

`(CH_(3))_(2)C(OH)CN, ( CH_(3))_(2)C=O`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the products A and B formed from the reaction of acetone with HCN followed by H3O+. Let's break this down step by step. ### Step 1: Identify the structure of acetone Acetone is a ketone with the formula \( \text{CH}_3\text{COCH}_3 \). Its structure can be represented as follows: ``` O || CH3-C-CH3 ``` ### Step 2: Reaction of acetone with HCN When acetone reacts with HCN (hydrogen cyanide), a nucleophilic addition reaction occurs. The cyanide ion (CN⁻) attacks the carbonyl carbon (C=O) of acetone, leading to the formation of a cyanohydrin. The product A can be represented as: ``` OH | CH3-C-CH3 | CN ``` This product is known as 2-hydroxy-2-methylpropanenitrile. ### Step 3: Reaction of product A with H3O+ When we add H3O⁺ (acidic medium) to the cyanohydrin, the nitrile group (CN) undergoes hydrolysis to form a carboxylic acid. The hydroxyl group (OH) remains, and the nitrile group is converted to a carboxylic acid group (COOH). The final product B can be represented as: ``` OH | CH3-C-CH3 | COOH ``` This product is known as 2-hydroxy-2-methylpropanoic acid. ### Conclusion Thus, the products A and B are: - A: 2-hydroxy-2-methylpropanenitrile (CH3)2C(OH)CN - B: 2-hydroxy-2-methylpropanoic acid (CH3)2C(OH)COOH ### Final Answer A is 2-hydroxy-2-methylpropanenitrile, and B is 2-hydroxy-2-methylpropanoic acid. ---
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES,KETONES & CARBOXYLIC ACIDS

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-L|10 Videos
  • ALDEHYDES,KETONES & CARBOXYLIC ACIDS

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-M|10 Videos
  • ALDEHYDES,KETONES & CARBOXYLIC ACIDS

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE-j|10 Videos
  • ALCOHOLS, PHENOLS & ETHERS

    VMC MODULES ENGLISH|Exercise Impeccable|100 Videos
  • AMINES

    VMC MODULES ENGLISH|Exercise IN CHAPTER EXERCISE H|10 Videos

Similar Questions

Explore conceptually related problems

(CH_(3))_(2)COoverset(NaCN)underset(HCI)rarr(A)underset(Delta)overset(H_(3)^(+)O)rarr(B) In the above sequence of reactions, (A) and (B) are :

Isopropylamine overset(KMnO_(4))rarr X overset(H_(3)^(+)O)rarr Y In the above sequence X and Y are

SiCl_4 overset (H_2O) (rarr) (X) overset (heat) (rarr)(Y) In the above reaction (X) and (Y) respectively are :

Alcohol overset(P + I_2)(rarr)X overset(Mg, dry,"ether")(rarr)Y overset(HCHO)(rarr)Z overset(H_2O //H^+)(rarr)2 - methylpropanol In this sequence of reaction, the starting alcohol is

The product D of the reaction CH_(3)Cl overset( KCN) ( rarr) ( A) overset( H_(2) O) ( rarr) (B) overset( NH_(3))(rarr) ( C ) overset( Delta)( rarr) ( D ) is

(CH_(3))_(2)CHOH overset("Mild")underset("oxidation[O]")rarr (X) overset((i)CH_(3)Mgl)underset((ii)"Hydrolysis")rarr (Y) In the above sequence of reaction, (Y) is:

N_2+H_2rarr[X](g)overset(CO_2,"Pressure")rarr[Y]overset("Heat")rarr[Z]+H_2O In the above sequence of reaction, [Y] and [Z] are respectively.

overset("SOCl"_(2))(rarr) (A) overset("KCN")(rarr) (B) overset(H^(+))(rarr) (C ), the compound (C ) is

"But-1-ene"overset((CH_(3)COO)_(2)Hg)underset(H_(3)O)rarr? The product in the above reaction is