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The vapure of a carboxylic acid HA when ...

The vapure of a carboxylic acid `HA` when passed over `MnO` at 573 K`yields Propanone. The acid `HA` is

A

Methanoic acid

B

Ethanoic acid

C

Propanoic acid

D

Butanoic acid

Text Solution

AI Generated Solution

The correct Answer is:
To determine the carboxylic acid \( HA \) that yields propanone when passed over manganese oxide (\( MnO \)) at 573 K, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Reaction**: - We know that the reaction involves a carboxylic acid \( HA \) being converted into propanone (\( CH_3COCH_3 \)) when passed over \( MnO \) at a specific temperature (573 K). 2. **Identifying the Product**: - The product of the reaction is propanone, which is a ketone with the structure \( CH_3COCH_3 \). 3. **Analyzing the Options**: - We have four options for the carboxylic acid: 1. Mythenoic acid 2. Ethenoic acid 3. Propenoic acid 4. Biotenoic acid 4. **Determining the Structure of Ethenoic Acid**: - Ethenoic acid (also known as acetic acid) has the formula \( CH_2=COOH \) and can be represented as \( CH_3COOH \). 5. **Reaction of Ethenoic Acid with \( MnO \)**: - When ethenoic acid is heated with \( MnO \), it undergoes oxidation. The reaction can be represented as: \[ CH_3COOH \xrightarrow{MnO, 573 K} CH_3COCH_3 + CO_2 + H_2O \] - This reaction shows that ethenoic acid yields propanone, carbon dioxide, and water. 6. **Conclusion**: - Since the reaction of ethenoic acid produces propanone, we conclude that the carboxylic acid \( HA \) is **ethenoic acid**. ### Final Answer: The acid \( HA \) is **ethenoic acid**.
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