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Which CH(3)COOH reacts with CH(3)-MgX, t...

Which `CH_(3)COOH` reacts with `CH_(3)-MgX`, then

A

`CH_(3)COX` is formed

B

Hydrocarbon is formed

C

Acetone is formed

D

Alcohol is formed

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of what happens when acetic acid (CH₃COOH) reacts with a Grignard reagent (CH₃MgX), we can break it down into a series of steps. ### Step-by-Step Solution: 1. **Identify the Reactants**: - We have acetic acid (CH₃COOH) and a Grignard reagent (CH₃MgX). The Grignard reagent consists of a methyl group (CH₃) bonded to magnesium (Mg) and a halogen (X). 2. **Understand the Nature of Grignard Reagents**: - Grignard reagents are highly reactive organometallic compounds. The carbon in CH₃MgX has a partial negative charge (due to its higher electronegativity compared to magnesium), while magnesium carries a partial positive charge. 3. **Reaction Mechanism**: - The carbon atom in the Grignard reagent (CH₃) acts as a nucleophile and attacks the electrophilic carbon in the carbonyl group of acetic acid (C=O). - This leads to the formation of a tetrahedral intermediate. 4. **Formation of Alkoxide**: - The tetrahedral intermediate collapses, resulting in the formation of an alkoxide ion (CH₃COO⁻MgX⁺) and the release of a methane molecule (CH₄). - The reaction can be summarized as: \[ \text{CH}_3\text{COOH} + \text{CH}_3\text{MgX} \rightarrow \text{CH}_3\text{COO}^-\text{MgX}^+ + \text{CH}_4 \] 5. **Final Product**: - The product formed is a magnesium salt of acetic acid (CH₃COO⁻MgX⁺) and methane (CH₄). The alkoxide (CH₃COO⁻) can further react with water to form acetic acid again, but in this case, we focus on the immediate products of the reaction. ### Conclusion: When acetic acid reacts with CH₃MgX, the products are methane (CH₄) and a magnesium salt of acetic acid (CH₃COO⁻MgX⁺).
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