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Product obtained by electrolytic reducti...

Product obtained by electrolytic reduction of nitrobenzene in presence of `H_2SO_4` s

A

o-amino phenol

B

m-amino phenol

C

p-amino phenol

D

None of these

Text Solution

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The correct Answer is:
To solve the question regarding the product obtained by the electrolytic reduction of nitrobenzene in the presence of H₂SO₄, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Reaction**: The question involves the electrolytic reduction of nitrobenzene. Nitrobenzene (C₆H₅NO₂) is a compound that contains a nitro group (-NO₂) attached to a benzene ring. 2. **Identify the Conditions**: The reduction is taking place in the presence of sulfuric acid (H₂SO₄), which is a strongly acidic medium. This can influence the reaction pathway. 3. **Electrolytic Reduction Process**: During the electrolytic reduction, the nitro group (-NO₂) is reduced. The reduction of nitrobenzene typically leads to the formation of an intermediate compound known as phenylhydroxylamine (C₆H₅NHOH). 4. **Rearrangement**: The phenylhydroxylamine can undergo rearrangement. In this case, it rearranges to form para-aminophenol (C₆H₄(NH₂)OH), which is the final product of the reaction. 5. **Final Product**: Therefore, the product obtained from the electrolytic reduction of nitrobenzene in the presence of H₂SO₄ is para-aminophenol. ### Conclusion: The correct answer to the question is para-aminophenol.
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