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Which of the following compound reacts w...

Which of the following compound reacts with chlorofom and a base of form phenyl isocyanide?

A

Phenol

B

Aniline

C

Benzene

D

Nitro benzene

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound reacts with chloroform (CHCl3) and a base to form phenyl isocyanide, we can follow these steps: ### Step 1: Identify the Reaction The reaction in question involves chloroform and a base. Specifically, we are looking for a compound that can react with chloroform in the presence of a strong base to yield phenyl isocyanide. ### Step 2: Recall the Specific Reaction From organic chemistry, we know that aniline (C6H5NH2) reacts with chloroform and a strong base (like KOH) to produce phenyl isocyanide. The reaction can be summarized as follows: \[ \text{Aniline} + \text{CHCl}_3 + 3 \text{KOH} \rightarrow \text{Phenyl isocyanide} + 3 \text{KCl} + 3 \text{H}_2\text{O} \] ### Step 3: Write the Balanced Equation The balanced equation for the reaction is: \[ \text{C}_6\text{H}_5\text{NH}_2 + \text{CHCl}_3 + 3 \text{KOH} \rightarrow \text{C}_6\text{H}_5\text{N} \equiv \text{C} + 3 \text{KCl} + 3 \text{H}_2\text{O} \] ### Step 4: Identify the Correct Compound Given the options, we need to identify which one is aniline. Aniline is a primary amine with the formula C6H5NH2. If one of the options is aniline, then it is the correct answer. ### Conclusion The compound that reacts with chloroform and a base to form phenyl isocyanide is **aniline**.
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