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The reduction of which of the following ...

The reduction of which of the following compound would yield secondary amine?

A

Alkyl nitrile

B

Carbylamine

C

Primary amine

D

Secondary nitro compound

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound, when reduced, yields a secondary amine, we can follow these steps: ### Step 1: Understand the Types of Amines Amines can be classified as primary, secondary, or tertiary based on the number of carbon groups attached to the nitrogen atom. A secondary amine has two carbon groups attached to the nitrogen. ### Step 2: Identify the Compounds We need to analyze the given compounds to see which one can be reduced to form a secondary amine. ### Step 3: Recognize the Reduction Process Reduction of certain compounds, such as isocyanides, can lead to the formation of secondary amines. Specifically, a carbamoyl compound (like isocyanide) when reduced can yield a secondary amine. ### Step 4: Apply Reduction to Methyl Isocyanide For example, if we take methyl isocyanide (CS3N), and reduce it using lithium aluminum hydride (LiAlH4), the reaction can be represented as follows: \[ \text{CS}_3\text{N} + \text{LiAlH}_4 \rightarrow \text{CS}_3\text{NH} + \text{other products} \] This results in the formation of dimethylamine (CS3)2NH, which is a secondary amine. ### Step 5: Conclusion Thus, the compound that yields a secondary amine upon reduction is methyl isocyanide (CS3N). Therefore, the correct option is option B. ---
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