Home
Class 12
CHEMISTRY
The dimensions of rate constant of a sec...

The dimensions of rate constant of a second order reaction involves :

A

time and concentration

B

neither time nor concentration

C

time only

D

concentration only

Text Solution

AI Generated Solution

The correct Answer is:
To determine the dimensions of the rate constant for a second-order reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Rate Law for a Second-Order Reaction:** The rate law for a second-order reaction can be expressed as: \[ \text{Rate} = k [A]^2 \] where \( k \) is the rate constant and \([A]\) is the concentration of the reactant. 2. **Identify the Units of Rate:** The rate of a reaction is typically expressed in terms of concentration change over time. The units of rate can be given as: \[ \text{Rate} = \frac{\text{moles}}{\text{liter} \cdot \text{second}} = \text{mol L}^{-1} \text{s}^{-1} \] 3. **Substitute the Units into the Rate Law:** From the rate law, we can rearrange to find the units of the rate constant \( k \): \[ k = \frac{\text{Rate}}{[A]^2} \] Substituting the units of rate and concentration: \[ k = \frac{\text{mol L}^{-1} \text{s}^{-1}}{(\text{mol L}^{-1})^2} \] 4. **Simplify the Units:** Simplifying the expression for \( k \): \[ k = \frac{\text{mol L}^{-1} \text{s}^{-1}}{\text{mol}^2 \text{L}^{-2}} = \frac{\text{mol L}^{-1} \text{s}^{-1}}{\text{mol}^2} \cdot \text{L}^2 = \frac{\text{L}}{\text{mol} \cdot \text{s}} \] 5. **Express the Dimensions:** The dimensions of the rate constant \( k \) can be expressed as: \[ [k] = \text{L} \cdot \text{mol}^{-1} \cdot \text{s}^{-1} \] 6. **Identify the Involved Dimensions:** From the final expression, we can see that the dimensions of the rate constant involve: - Concentration (mol) - Time (s) ### Final Answer: The dimensions of the rate constant of a second-order reaction involve time and concentration. ---

To determine the dimensions of the rate constant for a second-order reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Rate Law for a Second-Order Reaction:** The rate law for a second-order reaction can be expressed as: \[ \text{Rate} = k [A]^2 ...
Promotional Banner

Similar Questions

Explore conceptually related problems

The unit of rate constant for a second order reaction is

The rate constant for zero order reaction is

The unit of rate constant for a first order reaction

The unit of rate constant for zero order reaction is :

The value of rate constant of a pseudo first order reaction

The unit of rate constant for zero order reaction is :

Rate constant in case of first order reaction is