Home
Class 12
CHEMISTRY
The rate constant of a reaction has same...

The rate constant of a reaction has same units as the rate of reaction. The reaction is of:

A

zero order

B

first order

C

second order

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the order of the reaction based on the relationship between the rate constant (k) and the rate of reaction (R). The key point is that the units of k must be the same as the units of R. ### Step-by-Step Solution: 1. **Understanding Rate of Reaction**: The rate of a reaction (R) is defined as the change in concentration of a reactant or product per unit time. The units for rate are typically expressed as: \[ \text{Rate (R)} = \frac{\text{moles}}{\text{liter} \cdot \text{second}} = \text{mol L}^{-1} \text{s}^{-1} \] 2. **Rate Law Expression**: The rate law for a reaction can be expressed as: \[ R = k [A]^n \] where: - \( R \) is the rate of reaction, - \( k \) is the rate constant, - \([A]\) is the concentration of reactant A, - \( n \) is the order of the reaction. 3. **Analyzing Units for Different Orders**: - For **zero-order reactions** (\( n = 0 \)): \[ R = k \] Here, the rate constant \( k \) has the same units as the rate of reaction, which is \( \text{mol L}^{-1} \text{s}^{-1} \). - For **first-order reactions** (\( n = 1 \)): \[ R = k [A] \] Rearranging gives: \[ k = \frac{R}{[A]} \] The units of \( k \) become: \[ k = \frac{\text{mol L}^{-1} \text{s}^{-1}}{\text{mol L}^{-1}} = \text{s}^{-1} \] Here, the units of \( k \) are not the same as the units of \( R \). - For **second-order reactions** (\( n = 2 \)): \[ R = k [A]^2 \] Rearranging gives: \[ k = \frac{R}{[A]^2} \] The units of \( k \) become: \[ k = \frac{\text{mol L}^{-1} \text{s}^{-1}}{(\text{mol L}^{-1})^2} = \text{L mol}^{-1} \text{s}^{-1} \] Again, the units of \( k \) are not the same as the units of \( R \). 4. **Conclusion**: The only case where the units of the rate constant \( k \) and the rate of reaction \( R \) are the same is for a zero-order reaction. Therefore, the order of the reaction is: \[ \text{Order of the reaction} = 0 \] ### Final Answer: The reaction is of **zero order**.

To solve the problem, we need to determine the order of the reaction based on the relationship between the rate constant (k) and the rate of reaction (R). The key point is that the units of k must be the same as the units of R. ### Step-by-Step Solution: 1. **Understanding Rate of Reaction**: The rate of a reaction (R) is defined as the change in concentration of a reactant or product per unit time. The units for rate are typically expressed as: \[ \text{Rate (R)} = \frac{\text{moles}}{\text{liter} \cdot \text{second}} = \text{mol L}^{-1} \text{s}^{-1} ...
Promotional Banner

Similar Questions

Explore conceptually related problems

The rate constant of a reaction has same dimensions as rate of reaction The reaction is of

The rate constant of a reaction varies :

Assertion (A) : The rate constant of a zero order reaction has same units as the rate of reaction. Reason (R ): Rate constant of a zero order reaction does not depend upon the units of concentration.

The rate constant of a reaction changes with

The rate constant of a reaction is equal to the rate of reaction when

The rate constant of a reaction depends on

The rate constant for zero order reaction is

What do you understand by the rate law and rate constant of a reaction? Identify the order of a reaction if the units of its rate constant are :