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The rate constant of a reaction has same...

The rate constant of a reaction has same dimensions as rate of reaction The reaction is of

A

zero order

B

first order

C

second order

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, "The rate constant of a reaction has the same dimensions as the rate of reaction. The reaction is of:", we will analyze the relationship between the rate of reaction and the rate constant for different orders of reactions. ### Step-by-Step Solution: 1. **Understanding Rate of Reaction**: - The rate of a reaction is defined as the change in concentration of a reactant or product per unit time. The units for rate can be expressed as: \[ \text{Rate} = \frac{\Delta [\text{Concentration}]}{\Delta t} \] - The standard unit of concentration is moles per liter (mol/L), and the unit of time is seconds (s). Therefore, the units for rate are: \[ \text{Units of Rate} = \frac{\text{mol/L}}{\text{s}} = \text{mol L}^{-1} \text{s}^{-1} \] 2. **Rate Constant for Different Orders**: - The rate constant (k) has different units depending on the order of the reaction: - **Zero Order Reaction**: - Rate equation: \( R = k \) - Units of k: Same as rate = mol L\(^{-1}\) s\(^{-1}\) - **First Order Reaction**: - Rate equation: \( R = k[A] \) - Rearranging gives: \( k = \frac{R}{[A]} \) - Units of k: \( \frac{\text{mol L}^{-1} \text{s}^{-1}}{\text{mol L}^{-1}} = \text{s}^{-1} \) - **Second Order Reaction**: - Rate equation: \( R = k[A]^2 \) - Rearranging gives: \( k = \frac{R}{[A]^2} \) - Units of k: \( \frac{\text{mol L}^{-1} \text{s}^{-1}}{(\text{mol L}^{-1})^2} = \text{mol}^{-1} \text{L}^{1} \text{s}^{-1} \) 3. **Comparing Units**: - From the analysis: - For **Zero Order**: Units of k = mol L\(^{-1}\) s\(^{-1}\) (same as rate) - For **First Order**: Units of k = s\(^{-1}\) (not the same as rate) - For **Second Order**: Units of k = mol\(^{-1}\) L s\(^{-1}\) (not the same as rate) 4. **Conclusion**: - The only case where the rate constant (k) has the same dimensions as the rate of reaction is for a **zero order reaction**. Thus, the correct answer is **Zero Order Reaction**.

To solve the question, "The rate constant of a reaction has the same dimensions as the rate of reaction. The reaction is of:", we will analyze the relationship between the rate of reaction and the rate constant for different orders of reactions. ### Step-by-Step Solution: 1. **Understanding Rate of Reaction**: - The rate of a reaction is defined as the change in concentration of a reactant or product per unit time. The units for rate can be expressed as: \[ \text{Rate} = \frac{\Delta [\text{Concentration}]}{\Delta t} ...
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