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The rate of chemical reaction at constan...

The rate of chemical reaction at constant temperature is proportional to:

A

The amount of products formed

B

The product of masses of the reactants

C

The product of the molar concentration of the reactants

D

The mean free path of the reaction

Text Solution

AI Generated Solution

The correct Answer is:
To determine the relationship between the rate of a chemical reaction at constant temperature and various factors, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Reaction Rate**: The rate of a chemical reaction is generally expressed in terms of the concentrations of the reactants involved in the reaction. For a reaction of the form \( A + B \rightarrow C + D \), the rate can be expressed as: \[ \text{Rate} = k [A]^m [B]^n \] where \( k \) is the rate constant, and \( m \) and \( n \) are the orders of the reaction with respect to reactants A and B, respectively. 2. **Constant Temperature Implications**: When the temperature is held constant, the rate constant \( k \) also remains constant. This is because the rate constant is influenced by temperature, as described by the Arrhenius equation: \[ k = A e^{-\frac{E_a}{RT}} \] where \( E_a \) is the activation energy, \( R \) is the gas constant, and \( T \) is the temperature in Kelvin. 3. **Dependence on Concentration**: Since \( k \) is constant at a given temperature, the rate of the reaction is directly proportional to the concentrations of the reactants. Therefore, the rate of the reaction can be simplified to: \[ \text{Rate} \propto [A]^m [B]^n \] This means that the rate of the reaction depends on the product of the molar concentrations of the reactants. 4. **Evaluating Options**: Now, let's evaluate the provided options: - **Option 1**: Proportional to the amount of the product formed - Incorrect, as the rate depends on reactants. - **Option 2**: Proportional to the product of the masses of the reactants - Incorrect, as it depends on concentrations, not masses. - **Option 3**: Proportional to the product of the molar concentration of the reactants - Correct, as this is how reaction rates are expressed. - **Option 4**: Proportional to the mean free path of the reaction - Incorrect, as mean free path does not directly affect the rate at constant temperature. 5. **Conclusion**: The correct answer is that the rate of the chemical reaction at constant temperature is proportional to the product of the molar concentrations of the reactants.
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