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For the reaction 2N2O5 to 4NO2 +O2 rate...

For the reaction `2N_2O_5 to 4NO_2 +O_2` rate of reaction and rate constant are `1.04 xx 10^(-4)and 3.4 xx 10^(-5)sec^(-1)` respectively. The concentration of `N_2O_5` at that time will be :

A

1.732

B

3

C

3.06

D

`3.4 xx 10^(-5)`

Text Solution

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The correct Answer is:
To find the concentration of \( N_2O_5 \) at the given time for the reaction \( 2N_2O_5 \rightarrow 4NO_2 + O_2 \), we can follow these steps: ### Step 1: Identify the order of the reaction Given that the rate constant \( k \) has units of \( \text{s}^{-1} \), we can conclude that this is a first-order reaction. In a first-order reaction, the rate is directly proportional to the concentration of the reactant. ### Step 2: Write the rate law expression For a first-order reaction, the rate law can be expressed as: \[ \text{Rate} = k [N_2O_5] \] where: - Rate is the rate of the reaction, - \( k \) is the rate constant, - \( [N_2O_5] \) is the concentration of the reactant \( N_2O_5 \). ### Step 3: Substitute the known values We know: - Rate \( = 1.04 \times 10^{-4} \, \text{mol L}^{-1} \text{s}^{-1} \) - Rate constant \( k = 3.4 \times 10^{-5} \, \text{s}^{-1} \) Now, substituting these values into the rate law: \[ 1.04 \times 10^{-4} = 3.4 \times 10^{-5} [N_2O_5] \] ### Step 4: Solve for the concentration of \( N_2O_5 \) To find \( [N_2O_5] \), rearrange the equation: \[ [N_2O_5] = \frac{1.04 \times 10^{-4}}{3.4 \times 10^{-5}} \] ### Step 5: Calculate the concentration Now, performing the calculation: \[ [N_2O_5] = \frac{1.04}{3.4} \times 10^{-4 + 5} = \frac{1.04}{3.4} \times 10^{1} \] Calculating \( \frac{1.04}{3.4} \): \[ \frac{1.04}{3.4} \approx 0.30588 \] Thus, \[ [N_2O_5] \approx 0.30588 \times 10^{1} \approx 3.0588 \, \text{mol L}^{-1} \] ### Final Answer The concentration of \( N_2O_5 \) at that time will be approximately: \[ [N_2O_5] \approx 3.06 \, \text{mol L}^{-1} \] ---
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