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If reaction between A and B to give C sh...

If reaction between A and B to give C shows first order kinetics in A and second order in B, the rate equation can be written as

A

Rate = k[A]`[B]^(1//2)`

B

Rate = `[A]^(1//2)[B]`

C

Rate `=k[A][B]^2`

D

Rate `=k[A]^2[B]`

Text Solution

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The correct Answer is:
To derive the rate equation for the reaction between A and B to give C, we need to consider the order of the reaction with respect to each reactant. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction is given as: \[ A + B \rightarrow C \] 2. **Determine the Order of Reaction**: - The problem states that the reaction is **first order** in A. This means that the rate of the reaction is directly proportional to the concentration of A raised to the power of 1. - The reaction is **second order** in B. This means that the rate of the reaction is directly proportional to the concentration of B raised to the power of 2. 3. **Write the Rate Law Expression**: The rate law expression can be written as: \[ \text{Rate} = k [A]^m [B]^n \] where \( m \) is the order with respect to A and \( n \) is the order with respect to B. 4. **Substitute the Orders**: Given that \( m = 1 \) (first order in A) and \( n = 2 \) (second order in B), we can substitute these values into the rate law expression: \[ \text{Rate} = k [A]^1 [B]^2 \] 5. **Simplify the Rate Law**: The expression can be simplified to: \[ \text{Rate} = k [A] [B]^2 \] 6. **Conclusion**: Therefore, the rate equation for the reaction is: \[ \text{Rate} = k [A] [B]^2 \]
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