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Which one of the following does not repr...

Which one of the following does not represent Arrhenius equation?

A

`K = Ae^(-E/(RT))`

B

`log_ek = log_eA - E/(RT)`

C

`log_10k = log_10 A - E/(2.303RT)`

D

`k =AE^(-RT)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify which of the given options does not represent the Arrhenius equation. The Arrhenius equation is a fundamental equation in chemical kinetics that describes how the rate constant (k) of a reaction depends on temperature (T) and activation energy (E_A). ### Step-by-Step Solution: 1. **Understanding the Arrhenius Equation**: The Arrhenius equation is expressed as: \[ k = A e^{-\frac{E_A}{RT}} \] where: - \( k \) = rate constant - \( A \) = pre-exponential factor (frequency factor) - \( E_A \) = activation energy - \( R \) = universal gas constant - \( T \) = temperature in Kelvin 2. **Identifying Different Forms**: The Arrhenius equation can be manipulated into different forms. For example: - Taking the natural logarithm of both sides gives: \[ \ln k = \ln A - \frac{E_A}{RT} \] - This can also be converted to base 10 logarithm: \[ \log_{10} k = \log_{10} A - \frac{E_A}{2.303RT} \] 3. **Analyzing the Options**: We need to analyze the provided options to see which one does not match the standard forms of the Arrhenius equation. 4. **Identifying the Incorrect Option**: - If one of the options is written as: \[ k = A e^{-\frac{E}{RT}} \] where \( E \) is not specified as \( E_A \) (activation energy), it may imply that it represents a different context or is incorrectly stated. - If the option states something like \( k = A e^{-\frac{E}{RT}} \) without specifying \( E_A \), this could be misleading and does not represent the Arrhenius equation accurately. 5. **Conclusion**: After analyzing the options, the one that does not represent the Arrhenius equation is: \[ k = A e^{-\frac{E}{RT}} \] if \( E \) is not clearly defined as activation energy. ### Final Answer: The option that does not represent the Arrhenius equation is the one that states \( k = A e^{-\frac{E}{RT}} \) without specifying \( E_A \). ---
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