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Temperature dependent equation can be wr...

Temperature dependent equation can be written as:

A

`Ink =InA - E_a/(RT)`

B

`Ink = InA + e^(E_2//RT)`

C

`InK = InA -e^(RT//E_a)`

D

All of these

Text Solution

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The correct Answer is:
To solve the question regarding the temperature-dependent equation, we will derive the Arrhenius equation step by step. ### Step-by-Step Solution: 1. **Understand the Arrhenius Equation**: The Arrhenius equation describes how the rate constant (k) of a chemical reaction depends on temperature (T). It is given by the formula: \[ k = A e^{-\frac{E_a}{RT}} \] where: - \( k \) = rate constant - \( A \) = pre-exponential factor (frequency factor) - \( E_a \) = activation energy - \( R \) = universal gas constant - \( T \) = temperature in Kelvin 2. **Take the Natural Logarithm of Both Sides**: To linearize the equation, we take the natural logarithm (ln) of both sides: \[ \ln k = \ln A + \ln \left(e^{-\frac{E_a}{RT}}\right) \] Using the property of logarithms that states \(\ln(e^x) = x\), we can simplify this further. 3. **Simplify the Equation**: The equation becomes: \[ \ln k = \ln A - \frac{E_a}{RT} \] 4. **Final Form of the Temperature-Dependent Equation**: Thus, the temperature-dependent equation can be expressed as: \[ \ln k = \ln A - \frac{E_a}{RT} \] This is the required form of the temperature-dependent equation. 5. **Identify the Correct Option**: From the options provided, the correct expression is: \[ \ln k = \ln A - \frac{E_a}{RT} \] This corresponds to the first option given in the question. ### Conclusion: The temperature-dependent equation can be written as: \[ \ln k = \ln A - \frac{E_a}{RT} \]
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