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Silver Acetate + Br(2) overset(CS(2)) to...

Silver Acetate + `Br_(2) overset(CS_(2)) to` Main Product . The major product of this reaction is

A

`CH_(3)Br`

B

`CH_(3)COI`

C

`CH_(3)COOH`

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine the major product of the reaction between silver acetate and bromine in the presence of carbon disulfide (CS2), we can follow these steps: ### Step-by-Step Solution 1. **Identify the Reactants**: - The reactants are silver acetate (CH3COOAg) and bromine (Br2) in the solvent carbon disulfide (CS2). 2. **Structure of Silver Acetate**: - Silver acetate can be represented as CH3COOAg, where CH3 is the methyl group, COO is the acetate part, and Ag is the silver ion. 3. **Mechanism Initiation**: - In the presence of Br2, the acetate ion (OOCCH3) acts as a nucleophile due to the presence of the negatively charged oxygen. This nucleophile will attack one of the bromine atoms in Br2. 4. **Formation of Brominated Product**: - The attack of the acetate ion on Br2 leads to the cleavage of the Br-Br bond. One bromine atom attaches to the acetate, forming a brominated acetate intermediate (CH3COOBr) and releasing AgBr as a byproduct. 5. **Decarboxylation**: - The brominated acetate can undergo decarboxylation, where the acetate group (COO) loses carbon dioxide (CO2). This results in the formation of a methyl radical (CH3•). 6. **Formation of the Final Product**: - The methyl radical (CH3•) can then combine with the bromine radical (Br•) formed during the initial reaction, leading to the formation of methyl bromide (CH3Br). 7. **Conclusion**: - The major product of the reaction between silver acetate and bromine in the presence of carbon disulfide is methyl bromide (CH3Br). ### Final Answer: The major product of the reaction is **Methyl Bromide (CH3Br)**. ---
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