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Chloroform can be obtained from:...

Chloroform can be obtained from:

A

Methanol

B

Methanal

C

Propanol- 1

D

Propanol-2

Text Solution

AI Generated Solution

The correct Answer is:
To determine from which compound chloroform can be obtained, we will analyze the options provided: methanol, methanol (again), propanol 1, and propanol 2. ### Step-by-Step Solution: 1. **Identify the Structure of Chloroform**: Chloroform has the chemical formula CHCl3. To synthesize chloroform, we need a precursor that can provide the necessary carbon and functional groups. 2. **Analyze the Options**: - **Option A: Methanol (CH3OH)**: - Methanol has only one carbon atom. It cannot be converted to chloroform because it lacks the necessary carbon backbone. - **Option B: Methanol (HCHO)**: - This is formaldehyde, which also has only one carbon atom. Like methanol, it cannot be converted to chloroform. - **Option C: Propanol 1 (CH3CH2CH2OH)**: - Propanol 1 has three carbon atoms. However, the alcohol group (OH) is attached to a carbon that is connected to two other carbon atoms. This does not meet the criteria for conversion to chloroform. - **Option D: Propanol 2 (CH3CHOHCH3)**: - Propanol 2 has three carbon atoms, and the alcohol group is attached to a carbon that is connected to only one other carbon atom. This structure meets the criteria for conversion to chloroform. 3. **Conversion Process**: - Propanol 2 can undergo a series of reactions: - It reacts with bleaching powder (Ca(OCl)2) and undergoes hydrolysis to produce chlorine (Cl2). - The chlorine can then react with propanol 2 to form a ketone (CH3C(=O)CH3) and HCl. - The ketone can undergo further chlorination to form a trichloro compound. - Finally, this compound can be treated to produce chloroform (CHCl3). 4. **Conclusion**: - Based on the analysis, the correct answer is **Option D: Propanol 2**.
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