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The standard cell potential of: Zn(s) ...

The standard cell potential of:
`Zn(s) abs( Zn^(2+) (aq) )abs( Cu^(2+) (aq)) Cu (s)` cell is `1.10` V The maximum work obtained by this cell will be

A

`–106.15` kJ

B

`– 212.30` kJ

C

`–318.45` kJ

D

`– 424.60` kJ

Text Solution

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The correct Answer is:
To find the maximum work obtained by the given electrochemical cell, we can use the formula: \[ W_{\text{max}} = -nFE^\circ_{\text{cell}} \] where: - \( n \) = number of moles of electrons transferred in the reaction, - \( F \) = Faraday's constant (approximately \( 96500 \, \text{C/mol} \)), - \( E^\circ_{\text{cell}} \) = standard cell potential (given as \( 1.10 \, \text{V} \)). ### Step 1: Identify the number of electrons transferred (n) From the given cell reaction: \[ \text{Zn} (s) + \text{Cu}^{2+} (aq) \rightarrow \text{Zn}^{2+} (aq) + \text{Cu} (s) \] We see that zinc is oxidized to zinc ions, losing 2 electrons, and copper ions are reduced to copper, gaining 2 electrons. Therefore, the number of electrons transferred (\( n \)) is 2. ### Step 2: Use Faraday's constant (F) The value of Faraday's constant is: \[ F = 96500 \, \text{C/mol} \] ### Step 3: Substitute the values into the formula Now substituting the values into the formula for maximum work: \[ W_{\text{max}} = -nFE^\circ_{\text{cell}} = - (2) (96500 \, \text{C/mol}) (1.10 \, \text{V}) \] ### Step 4: Calculate the work done Calculating the above expression: \[ W_{\text{max}} = - (2) (96500) (1.10) = -212300 \, \text{J} \] ### Step 5: Convert joules to kilojoules To convert joules to kilojoules, we divide by 1000: \[ W_{\text{max}} = -212300 \, \text{J} \div 1000 = -212.3 \, \text{kJ} \] ### Final Answer The maximum work obtained by this cell is: \[ W_{\text{max}} = -212.3 \, \text{kJ} \] ---
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