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From different sets of data of t(1//2) a...

From different sets of data of `t_(1//2)` at diifferent initial concentrations say 'a' for a given reaction, the `[t_(1//2)xxqa]` is found to be constant. The order or reaction is :

A

0

B

1

C

2

D

3

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction based on the given information about the half-life (\(t_{1/2}\)) and the initial concentration (\(a\)), we will follow these steps: ### Step 1: Understand the relationship between half-life and concentration The half-life of a reaction is related to the initial concentration of the reactants. For a reaction of order \(n\), the relationship can be expressed as: \[ t_{1/2} \propto a^{(1-n)} \] where \(t_{1/2}\) is the half-life and \(a\) is the initial concentration. ### Step 2: Rearranging the relationship From the proportionality, we can express it in terms of a constant: \[ t_{1/2} \cdot a^{(n-1)} = \text{constant} \] This means that if we multiply the half-life by the initial concentration raised to the power of \(n-1\), we will get a constant value. ### Step 3: Analyze the given information According to the problem, it is stated that \(t_{1/2} \cdot a\) is a constant. This implies: \[ t_{1/2} \cdot a^{(n-1)} = \text{constant} \] Comparing this with the given information, we can set: \[ n - 1 = 1 \] ### Step 4: Solve for \(n\) From the equation \(n - 1 = 1\), we can solve for \(n\): \[ n = 2 \] This indicates that the reaction is of second order. ### Conclusion The order of the reaction is **2**. ---
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