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If the concentration of the reactants in...

If the concentration of the reactants in the elementary reaction 2A + B `to` C + D is increased three folds, the rate of the reaction will be increased by:

A

27 times

B

9 times

C

64 times

D

10 times

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given elementary reaction and how the rate of the reaction changes with the concentration of the reactants. ### Step-by-Step Solution: 1. **Identify the Reaction**: The given elementary reaction is: \[ 2A + B \rightarrow C + D \] 2. **Determine the Order of the Reaction**: For an elementary reaction, the order of the reaction is equal to its molecularity. Here, the molecularity can be calculated as the sum of the stoichiometric coefficients: - For \(2A\), the coefficient is 2. - For \(B\), the coefficient is 1. - Therefore, the total molecularity (and thus the order) is: \[ 2 + 1 = 3 \] 3. **Write the Rate Law**: The rate of the reaction can be expressed in terms of the concentrations of the reactants: \[ \text{Rate} (R) = k[A]^2[B]^1 \] where \(k\) is the rate constant, \([A]\) is the concentration of \(A\), and \([B]\) is the concentration of \(B\). 4. **Increase the Concentrations**: According to the problem, the concentrations of the reactants are increased threefold: - New concentration of \(A\) becomes \(3[A]\) - New concentration of \(B\) becomes \(3[B]\) 5. **Calculate the New Rate**: The new rate of the reaction (\(R'\)) with the increased concentrations is: \[ R' = k(3[A])^2(3[B])^1 \] Simplifying this: \[ R' = k \cdot 9[A]^2 \cdot 3[B] = 27k[A]^2[B] \] 6. **Determine the Factor by Which the Rate Increases**: To find out how many times the new rate \(R'\) is compared to the original rate \(R\): \[ \frac{R'}{R} = \frac{27k[A]^2[B]}{k[A]^2[B]} = 27 \] 7. **Conclusion**: The rate of the reaction increases by a factor of 27 when the concentrations of the reactants are increased threefold. ### Final Answer: The rate of the reaction will be increased by **27 times**. ---
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