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For the reaction H(2)(g) + Br(2)(g) rarr...

For the reaction `H_(2)(g) + Br_(2)(g) rarr 2HBr (g)` the experimental data suggested that `r = k[H_(2)][Br_(2)]^(1//2)`
The molecularity and order of the reaction are respectively:

A

`2,3//2`

B

`3//2,3//2`

C

1,1

D

`1,1//2`

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the molecularity and order of the reaction given by the equation: \[ H_2(g) + Br_2(g) \rightarrow 2HBr(g) \] The rate law provided is: \[ r = k[H_2][Br_2]^{1/2} \] ### Step 1: Determine the Molecularity Molecularity is defined as the total number of reactant species (atoms or molecules) that are involved in the rate-determining step of a reaction. For the reaction: - There is 1 molecule of \( H_2 \) - There is 1 molecule of \( Br_2 \) Thus, the total number of reactant species is: \[ \text{Molecularity} = 1 + 1 = 2 \] ### Step 2: Determine the Order of the Reaction The order of a reaction is determined by the sum of the powers of the concentration terms in the rate law expression. From the rate law: \[ r = k[H_2][Br_2]^{1/2} \] We can see that: - The exponent of \( [H_2] \) is 1. - The exponent of \( [Br_2] \) is \( \frac{1}{2} \). Now, we sum these exponents to find the order: \[ \text{Order} = 1 + \frac{1}{2} = \frac{3}{2} \] ### Conclusion Thus, the molecularity of the reaction is 2 and the order of the reaction is \( \frac{3}{2} \). ### Final Answer The molecularity and order of the reaction are respectively: **2, \( \frac{3}{2} \)**. ---
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