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Reactions: 2A+B+2C to D follows three me...

Reactions: `2A+B+2C to D` follows three mechanistic steps: `2A+B to X (slow)` `X+C to Y` (fast) `Y+C to D` (fast)
What is the molecularity of the rate determining step and the total order of the reaction?

A

3,2

B

3,3

C

5,2

D

5,3

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The correct Answer is:
To solve the problem, we need to analyze the given reaction and its mechanistic steps to determine the molecularity of the rate-determining step and the total order of the reaction. ### Step-by-Step Solution: 1. **Identify the Rate-Determining Step:** The first step of the reaction is given as: \[ 2A + B \rightarrow X \quad (\text{slow step}) \] Since this is the slow step, it is the rate-determining step. 2. **Determine the Molecularity of the Rate-Determining Step:** Molecularity is defined as the number of reactant molecules involved in an elementary reaction. In the rate-determining step: - There are 2 molecules of A. - There is 1 molecule of B. Therefore, the molecularity of the rate-determining step is: \[ \text{Molecularity} = 2 \, (\text{from } A) + 1 \, (\text{from } B) = 3 \] 3. **Write the Rate Law for the Reaction:** The rate law can be derived from the rate-determining step. Since the rate-determining step is: \[ 2A + B \rightarrow X \] The rate law can be expressed as: \[ \text{Rate} = k [A]^2 [B]^1 \] where \( k \) is the rate constant. 4. **Calculate the Total Order of the Reaction:** The total order of a reaction is the sum of the powers of the concentration terms in the rate law. From the rate law: - The order with respect to A is 2. - The order with respect to B is 1. Therefore, the total order of the reaction is: \[ \text{Total Order} = 2 + 1 = 3 \] ### Final Answers: - **Molecularity of the Rate-Determining Step:** 3 - **Total Order of the Reaction:** 3
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