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In a first order reaction A to B, if k i...

In a first order reaction A `to` B, if k is rate constant and initial concentration of the reactant A is 2 M then the half life of the reaction is:

A

`(log 2)/k`

B

`( log 2)/(ksqrt0.5)`

C

`(l n 2)/k`

D

`0.693/0.5k`

Text Solution

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The correct Answer is:
To solve the problem regarding the half-life of a first-order reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Concept of Half-Life**: - The half-life (t₁/₂) of a reaction is the time required for the concentration of a reactant to decrease to half of its initial concentration. 2. **Identify the Initial Concentration**: - The initial concentration of reactant A (A₀) is given as 2 M. 3. **Determine the Concentration at Half-Life**: - At half-life, the concentration of A (Aₜ) will be half of A₀: \[ Aₜ = \frac{A₀}{2} = \frac{2 \, \text{M}}{2} = 1 \, \text{M} \] 4. **Use the First-Order Reaction Formula**: - For a first-order reaction, the half-life is given by the formula: \[ t_{1/2} = \frac{0.693}{k} \] - Here, \( k \) is the rate constant. 5. **Substitute the Values**: - Since we are not given the value of \( k \), we will express the half-life in terms of \( k \): \[ t_{1/2} = \frac{0.693}{k} \] 6. **Select the Correct Option**: - From the options provided, we see that \( \frac{\ln 2}{k} \) is equivalent to \( \frac{0.693}{k} \) since \( \ln 2 \approx 0.693 \). - Therefore, the correct answer is: \[ t_{1/2} = \frac{\ln 2}{k} \] ### Final Answer: The half-life of the reaction is \( \frac{\ln 2}{k} \). ---
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