Home
Class 12
CHEMISTRY
The order of aciditic strength among the...

The order of aciditic strength among the given phenols is :

A

`III gt IV gt I gt II`

B

`I gt IV gt III gt II`

C

`II gt I gt III gt IV`

D

`IV gt III gt I gt II`

Text Solution

Verified by Experts

Due to attachment of electrons withdrawing groups like the nitro group on phenol the acidic strength increases, while attachment of electron donating groups causes the acidic strength to decrease. In given compounds, p-nitrophenol is more acidic then m-nitrophenol because at para-position`-NO_(2)` group shows more -I and -R effect than ortho and meta-positions.
Hence, `IV gt III` ( acidic strength). In phenol and p-cresol, phenol in more acidic than p-cresol because`-CH_(3)` group is an electron donating group, hence decreases the acidic strength. Thus, order of acidic strength of therefore `IV gt III gt I gt II`
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS, PHENOLS & ETHERS

    VMC MODULES ENGLISH|Exercise PRACTICE EXERCISE:1|21 Videos
  • ALCOHOLS, PHENOLS & ETHERS

    VMC MODULES ENGLISH|Exercise PRACTICE EXERCISE:2|12 Videos
  • ALCOHOLS, PHENOLS & ETHERS

    VMC MODULES ENGLISH|Exercise IN-CHAPTER EXERCISE - L|10 Videos
  • 13-14 HYDROGEN & S-BLOCK ELEMENT

    VMC MODULES ENGLISH|Exercise JEE Advanced Archive|48 Videos
  • ALCOHOLS, PHENOLS & ETHERS

    VMC MODULES ENGLISH|Exercise Impeccable|100 Videos

Similar Questions

Explore conceptually related problems

Correct order of acidic strength

Correct order of acidic strength:

The order of acidic strength for the following compounds is :-

The correct order of acidic strength is

The correct order of acidic strength is

Correct order of basic strength

Which of the following represents the correct order of the acidic strength in the given compounds ?

The correct order of acid strength is

VMC MODULES ENGLISH-ALCOHOLS, PHENOLS & ETHERS -Example
  1. Which of the following is soluble in water

    Text Solution

    |

  2. Ethyl alcohol is heated with conc. H(2)SO(4) at 170^(@)C. The product ...

    Text Solution

    |

  3. The compound that reacts fastest with Lucas reagent at room temperatu...

    Text Solution

    |

  4. Diethyl ether on heating with conc. HI gives two moles of:

    Text Solution

    |

  5. An industrial method for preparation of methanol is:

    Text Solution

    |

  6. Phenol when treated with excess of bromine water gives a white precipi...

    Text Solution

    |

  7. In CH(3)CH(2)OH, the bond that undegoes heterolytic clevage most read...

    Text Solution

    |

  8. Phenol reacts with bromine in carbon disulphide at low temperature to ...

    Text Solution

    |

  9. The products of combustion of an aliphatic thiol (RSH) at 298K are

    Text Solution

    |

  10. The order of aciditic strength among the given phenols is :

    Text Solution

    |

  11. (CH(3) )(3) CMgBr on reaction with D(2)O produces

    Text Solution

    |

  12. Benzenediazonium chloride on reaction with phenol in weakly ba...

    Text Solution

    |

  13. Among the following compounds, the strongest acid is :

    Text Solution

    |

  14. 1-propanol and 2-propanol can be best distinguished by :

    Text Solution

    |

  15. The compound will react most readily with NaOH of form methanol is :

    Text Solution

    |

  16. Text Solution

    |

  17. The following compound on hydrolysis in aqueous acetone will give :

    Text Solution

    |

  18. When phenyl magnesium bromide reacts with t-butanol the product would ...

    Text Solution

    |

  19. The best method to prepare cyclohexene form cyclohexanol is by using:

    Text Solution

    |

  20. (I) 1,2-Dihydroxy benzene (II) 1,3-Dihydroxy benzene (III) 1,4-Dih...

    Text Solution

    |