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The compound will react most readily wit...

The compound will react most readily with NaOH of form methanol is :

A

`(CH_(3))_(4)N^(+)I^(-)`

B

`CH_(3)OCH_(3)`

C

`(CH_(3))_(3)S^(+)I^(-)`

D

`(CH_(3))_(3)CI`

Text Solution

Verified by Experts

It is understood from previous lessons that positive nitrogen is a stronger acid as compared to positive sulphur, and shall accept the electron pair more readily on an internal nucleophilic attack of the `OH^(+)` ion.
`(CH_(3))_(4)N^(+)I^(-)+NaOH rarr (CH_(3))_(4)N^(+)OH^(-)+NaI,(CH_(3))_(4)N^(+)OH^(-) overset(Delta)rarr (CH_(3))_(3)N+CH_(3)OH`
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VMC MODULES ENGLISH-ALCOHOLS, PHENOLS & ETHERS -Example
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  5. An industrial method for preparation of methanol is:

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  8. Phenol reacts with bromine in carbon disulphide at low temperature to ...

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  9. The products of combustion of an aliphatic thiol (RSH) at 298K are

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  10. The order of aciditic strength among the given phenols is :

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  11. (CH(3) )(3) CMgBr on reaction with D(2)O produces

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  13. Among the following compounds, the strongest acid is :

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  14. 1-propanol and 2-propanol can be best distinguished by :

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  15. The compound will react most readily with NaOH of form methanol is :

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  19. The best method to prepare cyclohexene form cyclohexanol is by using:

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