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Which of the following is the best proce...

Which of the following is the best procedure to make isopropyl methyl ether using the Williamson's method ?

A

`CH_(3)OH+(CH_(3))_(2)CHOH+H_(2)SO_(4)`

B

`CH_(3)OH+(CH_(3))_(2)CHCH_(2)+H_(2)SO_(4)`

C

`CH_(2)ON a+(CH_(3))_(2)CHBr`

D

`CH_(3)I+(CH_(3))_(2)CHONa `)

Text Solution

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The correct Answer is:
To synthesize isopropyl methyl ether (CH3)2CHOCH3 using the Williamson synthesis method, we can follow these steps: ### Step 1: Identify the reactants In the Williamson synthesis, we need an alkoxide and an alkyl halide. For isopropyl methyl ether, we can identify: - **Alkoxide (R1O)**: Isopropyl alkoxide, which is derived from isopropanol (CH3)2CHO. - **Alkyl halide (R2X)**: Methyl iodide (CH3I) is a suitable choice for the alkyl halide. ### Step 2: Prepare the alkoxide To prepare the isopropyl alkoxide, we can react isopropanol with sodium (Na): - **Reaction**: (CH3)2CHOH + Na → (CH3)2CHO⁻Na⁺ + ½ H2 This forms the isopropyl alkoxide (CH3)2CHO⁻Na⁺. ### Step 3: React the alkoxide with the alkyl halide Now, we will react the prepared isopropyl alkoxide with methyl iodide: - **Reaction**: (CH3)2CHO⁻Na⁺ + CH3I → (CH3)2CHOCH3 + NaI In this step, the alkoxide attacks the methyl halide, resulting in the formation of isopropyl methyl ether and sodium iodide as a byproduct. ### Step 4: Final product The final product of the reaction is isopropyl methyl ether (CH3)2CHOCH3. ### Conclusion The best procedure to make isopropyl methyl ether using the Williamson method involves preparing isopropyl alkoxide from isopropanol and then reacting it with methyl iodide. ---

To synthesize isopropyl methyl ether (CH3)2CHOCH3 using the Williamson synthesis method, we can follow these steps: ### Step 1: Identify the reactants In the Williamson synthesis, we need an alkoxide and an alkyl halide. For isopropyl methyl ether, we can identify: - **Alkoxide (R1O)**: Isopropyl alkoxide, which is derived from isopropanol (CH3)2CHO. - **Alkyl halide (R2X)**: Methyl iodide (CH3I) is a suitable choice for the alkyl halide. ### Step 2: Prepare the alkoxide ...
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