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C(6)H(5)OH+ClCOCH(3) overset("Aq. NaOH")...

`C_(6)H_(5)OH+ClCOCH_(3) overset("Aq. NaOH")rarr C_(6)H_(5)COOCH_(3)` is an example of

A

Dow's reaction

B

Reimer-Tiemann reaction

C

Schotten-Baumann reaction

D

Kolbe's reaction

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question `C_(6)H_(5)OH + ClCOCH_(3) overset("Aq. NaOH")rarr C_(6)H_(5)COOCH_(3)`, we need to identify the type of reaction occurring here. ### Step-by-Step Solution: 1. **Identify the Reactants:** - The first reactant is phenol, represented as \( C_6H_5OH \). - The second reactant is chloroacetone, represented as \( ClCOCH_3 \). 2. **Understand the Reaction Conditions:** - The reaction is carried out in the presence of aqueous sodium hydroxide (NaOH). This indicates that it is a nucleophilic substitution reaction, as NaOH is a strong base and can deprotonate phenol to form a phenoxide ion. 3. **Formation of Phenoxide Ion:** - When phenol reacts with NaOH, it forms the phenoxide ion \( C_6H_5O^- \). This ion is a stronger nucleophile compared to phenol itself. 4. **Nucleophilic Attack:** - The phenoxide ion then attacks the carbon atom in chloroacetone that is bonded to the chlorine atom. This is a typical nucleophilic substitution reaction where the nucleophile (phenoxide ion) replaces the leaving group (chlorine). 5. **Formation of the Product:** - The product formed from this reaction is \( C_6H_5COOCH_3 \), which is an ether (specifically an aryl ether) where the phenol has reacted with chloroacetone. 6. **Identify the Type of Reaction:** - The reaction is classified as a **Sodium Berman Reaction**. This is a specific type of nucleophilic substitution reaction involving phenols and alkyl halides. ### Final Answer: The reaction `C_(6)H_(5)OH + ClCOCH_(3) overset("Aq. NaOH")rarr C_(6)H_(5)COOCH_(3)` is an example of **Sodium Berman Reaction**. ---
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