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With oxalic acid, glycerol at 260^(@)C g...

With oxalic acid, glycerol at `260^(@)`C gives:

A

Allyl alcohol

B

Glyceryl mono-oxalate

C

Formic acid

D

Glyceraldehyde

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of glycerol with oxalic acid at 260°C, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants in this reaction are glycerol (C3H8O3) and oxalic acid (C2H2O4). 2. **Understand the Reaction Conditions**: - The reaction takes place at a high temperature of 260°C, which is significant for driving dehydration and decarboxylation reactions. 3. **Dehydration Process**: - When glycerol is heated with oxalic acid, two water molecules are removed. This dehydration step leads to the formation of an intermediate compound known as glycerol dioxalate. \[ \text{Glycerol} \rightarrow \text{Glycerol dioxalate} + 2 \text{H}_2\text{O} \] 4. **Formation of Glycerol Dioxalate**: - The structure of glycerol dioxalate can be represented as: \[ \text{CH}_2\text{OOC}-\text{CHOOC}-\text{CH}_2\text{OH} \] 5. **Decarboxylation Process**: - Upon further heating, the glycerol dioxalate undergoes decarboxylation, where two carbon dioxide (CO2) molecules are released. \[ \text{Glycerol dioxalate} \rightarrow \text{Allyl alcohol} + 2 \text{CO}_2 \] 6. **Final Product Formation**: - The final product formed from this reaction is allyl alcohol (C3H6O), which has the structure: \[ \text{CH}_2=CH-\text{CH}_2\text{OH} \] 7. **Conclusion**: - Therefore, the product formed when glycerol reacts with oxalic acid at 260°C is allyl alcohol. ### Final Answer: The correct answer is **allyl alcohol**. ---
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