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In the excess of air, the major oxides f...

In the excess of air, the major oxides formed by Li, Na and K are `Li_(2)O, Na_(2)O_(2)` and `KO_(2)` respectively. Arrange all the given oxides in the decreasing order of their stability.

A

`Li_(2)O gt Na_(2)O_(2)gt KO_(2)`

B

`KO_(2)gt Na_(2)O_(2)gt Li_(2)O`

C

`Na_(2)O_(2)gt KO_(2)gt Li_(2)O`

D

`Li_(2)O gt KO_(2)gt Na_(2)O_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the stability of the oxides formed by lithium (Li), sodium (Na), and potassium (K) in the presence of excess air, we need to analyze the oxides: \( Li_2O \), \( Na_2O_2 \), and \( KO_2 \). ### Step-by-Step Solution: 1. **Identify the Oxides**: - Lithium forms \( Li_2O \) (lithium oxide). - Sodium forms \( Na_2O_2 \) (sodium peroxide). - Potassium forms \( KO_2 \) (potassium superoxide). 2. **Understand the Types of Oxides**: - \( Li_2O \) is a simple oxide. - \( Na_2O_2 \) is a peroxide, which contains the peroxide ion \( O_2^{2-} \). - \( KO_2 \) is a superoxide, which contains the superoxide ion \( O_2^{-} \). 3. **Stability of Oxides**: - The stability of these oxides generally decreases as we move from simple oxides to peroxides and then to superoxides. - This is because larger cations can stabilize larger anions better. Thus, the stability order is influenced by the size of the metal ions and the type of anion. 4. **Comparison of Stability**: - \( Li_2O \) is the most stable because lithium is the smallest cation and can effectively stabilize the oxide ion. - \( Na_2O_2 \) is less stable than \( Li_2O \) because the peroxide ion is larger and less stable than the oxide ion. - \( KO_2 \) is the least stable due to the presence of the superoxide ion, which is even larger and less stable compared to the peroxide ion. 5. **Final Arrangement**: - Based on the analysis above, the decreasing order of stability is: \[ Li_2O > Na_2O_2 > KO_2 \] ### Final Answer: The decreasing order of stability of the oxides is: \[ Li_2O > Na_2O_2 > KO_2 \]

To determine the stability of the oxides formed by lithium (Li), sodium (Na), and potassium (K) in the presence of excess air, we need to analyze the oxides: \( Li_2O \), \( Na_2O_2 \), and \( KO_2 \). ### Step-by-Step Solution: 1. **Identify the Oxides**: - Lithium forms \( Li_2O \) (lithium oxide). - Sodium forms \( Na_2O_2 \) (sodium peroxide). - Potassium forms \( KO_2 \) (potassium superoxide). ...
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