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Which one of the following statements re...

Which one of the following statements regarding Henry’s law is not correct?

A

Higher the value of `K_(H)` at a given pressure, higher is the solubility of the gas in the liquids

B

The value of `K_(H)` increases with increase of temperature and `K_(H)` is function of the nature of the gas

C

Different gases have different `K_(H)` (Henry’s law constant) values at the same temperature

D

The partial pressure of the gas in vapour phase is proportional to the mole fraction of the gas in the solution

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement regarding Henry's law is not correct, we need to analyze each option provided: 1. **Understanding Henry's Law**: Henry's law states that the amount of gas that dissolves in a liquid at a given temperature is directly proportional to the partial pressure of that gas above the liquid. This can be expressed mathematically as: \[ P = k_H \cdot x \] where \( P \) is the partial pressure of the gas, \( k_H \) is Henry's law constant, and \( x \) is the mole fraction of the gas in the solution. 2. **Analyzing Each Statement**: - **Statement A**: "Higher the value of \( k_H \) at a given pressure, higher is the solubility of the gas in the liquids." - This statement is incorrect. A higher value of \( k_H \) actually indicates lower solubility of the gas in the liquid. Therefore, as \( k_H \) increases, the solubility decreases. - **Statement B**: "The value of \( k_H \) increases with increase of temperature and \( k_H \) is a function of the nature of the gas." - This statement is correct. Generally, as temperature increases, the solubility of gases in liquids decreases, leading to an increase in \( k_H \). - **Statement C**: "Different gases have different \( k_H \) Henry's law constant values at the same temperature." - This statement is also correct. Each gas has a unique \( k_H \) value based on its properties. - **Statement D**: "The partial pressure of the gas in the vapor phase is proportional to the mole fraction of the gas in the solution." - This statement is correct and aligns with the definition of Henry's law. 3. **Conclusion**: The only incorrect statement is **Statement A**. ### Final Answer: The incorrect statement regarding Henry's law is: **A. Higher the value of \( k_H \) at a given pressure, higher is the solubility of the gas in the liquids.**

To determine which statement regarding Henry's law is not correct, we need to analyze each option provided: 1. **Understanding Henry's Law**: Henry's law states that the amount of gas that dissolves in a liquid at a given temperature is directly proportional to the partial pressure of that gas above the liquid. This can be expressed mathematically as: \[ P = k_H \cdot x \] where \( P \) is the partial pressure of the gas, \( k_H \) is Henry's law constant, and \( x \) is the mole fraction of the gas in the solution. ...
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