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Match List-I with List-II and choose the...

Match List-I with List-II and choose the correct matching codes from the choices given.
`{:(,"List-I",,"List-II"),("A.",PCl_(5),1.,"Linear"),("B.",IF_(7),2.,"pyramidal"),("C.",H_(3)O^(+),3.,"Trigonal bipyramidal"),("D.",ClO_(2),4.,"Tetrahedral"),("E.",NH_(4)^(+),5.,"Pentagonal bipyramidal"),(,,6.,"Angular"):}`

A

A-3, B-5, C-2, D-1, E-4

B

A-3, B-5, C-4, D-1, E-2

C

A-3, B-5, C-6, D-1, E-2

D

A-3, B-5, C-2, D-6, E-4

Text Solution

Verified by Experts

The correct Answer is:
D
`PCl_(5)=sp^(3)d` (Trigonal pyramidal)
`IF_(7)=sp^(3)d^(3)` (Pentagonal bipyramidal)
`H_(3)O^(+)=sp^(3)` (Pyramidal)
`ClO_(2)=sp^(2)` (Angular) bond length are shorter than single bond due to resonance.
`NH_(4)^(+)=sp^(3)` (Tetrahedral)
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