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Which one of the following on hydrolysis...

Which one of the following on hydrolysis, gives the corresponding metallic hydroxide, `H_(2)O_(2) and O_(2)` ?

A

`Li_(2)O`

B

`Na_(2)O_(2)`

C

`NaO_(2)`

D

`Na_(2)O`

Text Solution

Verified by Experts

The correct Answer is:
C

On hydrolysis, alkali metal oxides give the corresponding metallic hydroxides.
`Li_(2)O + H_(2)O rarr 2LiOH`
`Na_(2)O + H_(2)O rarr 2NaOH`
The peroxides of alkali metals give the corresponding metallic hydroxide and `H_(2)O_(2)`.
`Na_(2)O_(2) + 2H_(2)O rarr 2NaOH + H_(2)O_(2)`
Whereas, the superoxides of alkali metals give the corresponding metallic hydroxide, `H_(2)O_(2) and O_(2)`.
`2NaO_(2) + 2H_(2)O rarr 2NaOH + H_(2)O_(2) + O_(2)`
`Be(OH)_(2)` cannot be prepared by hydrolysis of BeO, as it is insoluble in water.
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