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Which will undergo S(N)2 reaction fastes...

Which will undergo `S_(N)2` reaction fastest among the following halogen compounds?

A

`CH_(3)CH_(2)F`

B

`CH_(3)CH_(2)Cl`

C

`CH_(3)CH_(2)Br`

D

`CH_(3)CH_(2)I`

Text Solution

Verified by Experts

The correct Answer is:
D

`S_(N)2` reactions involve the formation of intermediate transition state, thus less hindered alkyl halide readily undergoes `S_(N)2` reaction.
Moreover, C-I bond is less stable than C-Br or C-Cl bond, thus alkyl iodides are more reactive as compared to other halides.
Hence, `CH_(3)CH_(2)I` is most reactive towards `S_(N)2` reaction.
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