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Choose the weakest acid among the follow...

Choose the weakest acid among the following

A

`F_(3)C - COOH`

B

`F-CH_(2)-COOH`

C

`CH_(3)-COOH`

D

`(CH_(3))_(2)CH-COOH`

Text Solution

Verified by Experts

The correct Answer is:
D

The acidity of carboxylic acids depends upon the nature of the alkly group attached to -COOH. The presence of an electron-withdrawing (-I effect) group weakens the O-H bond in the acid and increases the acidity, while the presence of an electron releasing (+I effect) group strengthens the O-H bond of acid and thus, decreases the acidity. Thus, the weakest acid is,
`underset("2-methylpropanoic acid")(CH_(3)-overset(CH_(3))overset(|)(CH)-COOH)`
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