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Which of the following changes in the re...

Which of the following changes in the respective bond order values are caused by removal of an electron from `N_(2)andF_(2)` molecules?

A

Decrease by 0.5 in both

B

Increase by 0.5 in both

C

Increase by 0.5 in the former and decreases by 0.5 in ther latter

D

Decrease by 0.5 in the former and increase by 0.5 in the latter

Text Solution

Verified by Experts

The correct Answer is:
C

`N_(2)` (total electrons = 14)
`sigma1s^(2),sigma1s^(2),sigma2s^(2),sigma2s^(2),pi2p_(x)^(2)=pi2p_(y)^(2),sigma2p_(z)^(2)`
`F_(2)` (total electrons = 18)
`sigma1s^(2),sigma1s^(2),sigma2s^(2),sigma2s^(2),sigma2p_(z)^(2),pi2p_(x)^(2)=pi2p_(y)^(2),pi2p_(x)^(2)=pi2p_(y)^(2)`
For `N_(2)` the valence orbital is bonding molecular orbital and for `F_(2)`, it is antibonding molecular orbital.
So, bond order decrease by 0.5 in the former and increase by 0.5 in the water.
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