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For two isomorphous crystals A and B, th...

For two isomorphous crystals A and B, the ratio of density of A to that of B is 1.6. While the ratio of the edge length of B to that of A is 2. If the molar mass of crystal B is 200 g `mol^(-1)`, then that of crystal A is

A

240 g `"mol"^(-1)`

B

40 g `"mol"^(-1)`

C

80 g `"mol"^(-1)`

D

160 g `"mol"^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
B

Density of crystal lattice is directly proportional to molar mass and inversely proportional to edge length `dpropM/(a^(3))`. If density and molar mass of isomorphous crystal (A) are `d_(A)andM_(A)`, density and molar mass of isomorphous crystal (B) are `d_(B)andM_(B)` respectively.
then, `d_(A)/(d_(B))=M_(A)/(M_(B))xx(a_(B)/(a_(A)))^(3)`
Given, `M_(A)=?,M_(B)=200"g/mol"`
`d_(A)/(d_(B))=1.6,a_(B)/(a_(A))=2`
`m_(A)=(1.6xx200)/(8)=40"g/mol"`
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