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In the In K vs. (1)/(T) plot of a chemi...

In the In K vs. `(1)/(T)` plot of a chemical process having `triangle S^(0) gt 0` and `triangle H^(@) lt 0` the slope is proportional to (where k is equilibrium constant )

A

`-|triangleH^(@)|`

B

`|triangleH^(@)|`

C

`triangleS^(@)`

D

`-triangleS^(@)|`

Text Solution

Verified by Experts

The correct Answer is:
B

log k =log A-`(Ea)/(2.303R).(1)/(T)`
and `triangle G =triangleH-T triangleS=2.303 Rt log k`
on ploting the graph between `(1)/(T)` and log k using straight line equation

`y=mx+c`
`log k prop (1)/(T)`
The slope is proportion to `|triangleH^(@)|`
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