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Stannous sulphate (SnSO4) and potassium ...

Stannous sulphate `(SnSO_4)` and potassium permanganate are used as oxidising agents in acidic medium for oxidation of ferrous ammonium sulphate to ferric sulphate. The ratio of number of moles of stannous sulphate required per mole of ferrous ammounium sulphate to the number of moles of `KMnO_4` required per mole of ferrous ammonium sulphate, is :

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Stannous sulphate (SnSO_(4)) and potassium permanganate are used as oxidising agents in acidic medium for oxidation of ferrrous ammnium sulphate to ferric sulphate. The ration of number of moles of stannous sulphate required per mole of ferrous ammonium sulphate to the number of moles of KMnO_(4) required per mole of ferrous ammonium sulphate, is:

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"Equivalent mass" =("Molecular mass/Atomic mass" )/("n-factor") n-factor is very important in redox as well as non-redox reactions. With the help of n-factor we can predict the molar ratio of the reactant species taking part in reactions. The reciprocal of n-factor's ratio of the reactions is the molar ratio of the reactants. In general n-factor of acid/base is number of moles of H^(+)//OH^(-) furnished per mole of acid/base n-factor of a reactant is number of moles electrons lost or gained per mole of reactant. Example 1: (1)In acidic medium : KMnO_(4) (n=5)to Mn^(2+) (2) In neutral medium : KMnO_(4)(n=3) to Mn^(2+) (3) In basic medium : KMnO_(4)(n=1) to Mn^(6+) Example 2 : FeC_(2)O_(4)to Fe^(3+)+2CO_(2) Total number of moles e^(-) lost by 1 mole of FeC_(2)O_(4) =1+1xx2 implies 3 n-factor of Ba(MNO_(4))_(2) in acidic medium is :