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The number of species among the followin...

The number of species among the following,having magnetic moment value of 2.84 BM is_______.
`Fe^(2+), Cr, Cr^(3+), Ti^(2+), Mn^(2+), V^(3+)`

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To determine the number of species among the given ions that have a magnetic moment value of 2.84 Bohr Magneton (BM), we need to analyze the electronic configurations and the number of unpaired electrons for each species. ### Step-by-Step Solution: 1. **Understanding Magnetic Moment**: The magnetic moment (μ) is given by the formula: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. We need to find \( n \) such that \( \mu = 2.84 \) BM. 2. **Setting Up the Equation**: Plugging in the magnetic moment value: \[ 2.84 = \sqrt{n(n + 2)} \] Squaring both sides gives: \[ 2.84^2 = n(n + 2) \] \[ 8.0656 = n^2 + 2n \] Rearranging gives: \[ n^2 + 2n - 8.0656 = 0 \] 3. **Solving the Quadratic Equation**: Using the quadratic formula \( n = \frac{-b \pm \sqrt{b^2 - 4ac}}{2a} \): Here, \( a = 1, b = 2, c = -8.0656 \). \[ n = \frac{-2 \pm \sqrt{2^2 - 4 \cdot 1 \cdot (-8.0656)}}{2 \cdot 1} \] \[ n = \frac{-2 \pm \sqrt{4 + 32.2624}}{2} \] \[ n = \frac{-2 \pm \sqrt{36.2624}}{2} \] \[ n = \frac{-2 \pm 6.02}{2} \] This gives us \( n \approx 2 \) (since \( n \) must be a non-negative integer). 4. **Analyzing Each Species**: Now we will analyze each species to find the number of unpaired electrons: - **Fe²⁺**: - Electron configuration: [Ar] 4s² 3d⁶ → Fe²⁺: [Ar] 3d⁶ - Unpaired electrons: 4 (not suitable). - **Cr**: - Electron configuration: [Ar] 4s² 3d⁵ - Unpaired electrons: 6 (not suitable). - **Cr³⁺**: - Electron configuration: [Ar] 4s² 3d⁵ → Cr³⁺: [Ar] 3d³ - Unpaired electrons: 3 (not suitable). - **Ti²⁺**: - Electron configuration: [Ar] 4s² 3d² → Ti²⁺: [Ar] 3d² - Unpaired electrons: 2 (suitable). - **Mn²⁺**: - Electron configuration: [Ar] 4s² 3d⁵ → Mn²⁺: [Ar] 3d⁵ - Unpaired electrons: 5 (not suitable). - **V³⁺**: - Electron configuration: [Ar] 4s² 3d³ → V³⁺: [Ar] 3d² - Unpaired electrons: 2 (suitable). 5. **Conclusion**: The species with 2 unpaired electrons are Ti²⁺ and V³⁺. Therefore, the number of species having a magnetic moment value of 2.84 BM is **2**. ### Final Answer: The number of species among the following having a magnetic moment value of 2.84 BM is **2** (Ti²⁺ and V³⁺).
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