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Choose the correct order of ionic radius...

Choose the correct order of ionic radius for the following species. 

A

`CI^(-) gt I^(-) gt Te^(2-) gt Ar^(+)`

B

`Te^(2-) gt I^(-) gt Cl^(-) gt Ar^(+)`

C

`I^(-) gt Te^(2-) gt Cl^(-) gt Ar^(+)`

D

`I^(-) gt Cl^(-) gt Ar^(+) gt Te^(2-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of ionic radius for the species Cl⁻, I⁻, Te²⁻, and Ar⁺, we can follow these steps: ### Step 1: Identify the Ions and Their Charges The ions we are dealing with are: - Cl⁻ (Chloride ion) - I⁻ (Iodide ion) - Te²⁻ (Telluride ion) - Ar⁺ (Argon cation) ### Step 2: Determine the Group and Period of Each Ion - Cl⁻ and I⁻ are from Group 17 (the halogens). - Te²⁻ is from Group 16 (the chalcogens). - Ar⁺ is from Group 18 (the noble gases). ### Step 3: Analyze the Ionic Sizes 1. **Trends in Ionic Size**: - Ionic size increases down a group due to the addition of electron shells. - Ionic size decreases across a period from left to right due to increasing nuclear charge, which pulls electrons closer to the nucleus. 2. **Comparing the Ions**: - Te²⁻ has the largest ionic radius because it is in Group 16 and has gained two electrons, leading to increased electron-electron repulsion. - I⁻ is next; it is larger than Cl⁻ due to being below it in the group. - Cl⁻ is larger than Ar⁺ because Cl⁻ has an extra electron compared to Ar⁺, which has lost one electron, reducing its size due to increased nuclear charge acting on fewer electrons. ### Step 4: Establish the Order of Ionic Radii Based on the analysis: - Te²⁻ > I⁻ > Cl⁻ > Ar⁺ ### Conclusion The correct order of ionic radius for the species is: **Te²⁻ > I⁻ > Cl⁻ > Ar⁺**
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