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Choose the correct order of radius for t...

Choose the correct order of radius for the following species. 

A

`Na^(+) lt Na lt Na^(-)`

B

`Na^(-) gt Na^(+) gt Na`

C

`Na lt Na^(-) lt Na^(+)`

D

`Na lt Na^(+) lt Na^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of radius for the species Sodium positive (Na⁺), Sodium (Na), and Sodium negative (Na⁻), we need to analyze the effect of electron loss or gain on the atomic radius of these species. ### Step-by-Step Solution: 1. **Identify the Atomic Numbers**: - Sodium (Na) has an atomic number of 11, meaning it has 11 protons and 11 electrons. - Sodium positive (Na⁺) has lost one electron, so it has 10 electrons but still has 11 protons. - Sodium negative (Na⁻) has gained one electron, so it has 12 electrons and still has 11 protons. 2. **Understand the Concept of Nuclear Charge**: - The nuclear charge is the total charge of the nucleus, which is equal to the number of protons. - For Na⁺, the nuclear charge is 11 (from 11 protons) acting on 10 electrons. - For Na, the nuclear charge is 11 acting on 11 electrons. - For Na⁻, the nuclear charge is 11 acting on 12 electrons. 3. **Analyze the Effect of Electron Count on Atomic Radius**: - In Na⁺, with 11 protons and only 10 electrons, the effective nuclear charge is higher per electron. This means the electrons are pulled closer to the nucleus, resulting in a smaller radius. - In Na, with 11 protons and 11 electrons, the effective nuclear charge is balanced, resulting in a moderate radius. - In Na⁻, with 11 protons and 12 electrons, the effective nuclear charge is lower per electron. This means the outermost electron experiences less attraction from the nucleus, leading to a larger radius. 4. **Establish the Order of Radius**: - Based on the analysis: - Na⁺ has the smallest radius (due to higher effective nuclear charge). - Na has a moderate radius. - Na⁻ has the largest radius (due to lower effective nuclear charge). - Therefore, the correct order of radius is: **Na⁺ < Na < Na⁻** ### Final Answer: The correct order of radius is: **Na⁺ < Na < Na⁻**
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