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Choose the incorrect order for acidic st...

Choose the incorrect order for acidic strength.

A

`CO_2 gt CO`

B

`SO_2 gt SO_3`

C

`HClO_2 gt HOCl`

D

`SiO_2 gt CO_2`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the incorrect order of acidic strength from the given compounds, we will analyze the acidic properties of each compound step-by-step. ### Step 1: Analyze CO2 and CO - **Oxidation States**: In CO2, carbon has an oxidation state of +4 (C: +4, O: -2). In CO, carbon has an oxidation state of +2 (C: +2, O: -2). - **Acidity**: CO2 is more acidic than CO because it has a higher oxidation state, which means it has a greater tendency to accept electrons. ### Step 2: Analyze SO2 and SO3 - **Oxidation States**: In SO2, sulfur has an oxidation state of +4, while in SO3, sulfur has an oxidation state of +6. - **Acidity**: SO3 is more acidic than SO2 due to the higher oxidation state of sulfur in SO3, which allows it to accept more electrons. ### Step 3: Analyze HClO2 and HOCl - **Oxidation States**: In HClO2, chlorine has an oxidation state of +3, while in HOCl, chlorine has an oxidation state of +1. - **Acidity**: HClO2 is more acidic than HOCl because of the higher oxidation state of chlorine in HClO2. ### Step 4: Analyze SiO2 and CO2 - **Oxidation States**: Both SiO2 and CO2 have silicon and carbon in the +4 oxidation state, respectively. - **Acidity**: However, CO2 is more acidic than SiO2. This is because carbon is more electronegative than silicon, leading to a greater tendency for CO2 to accept electrons. ### Conclusion Based on the analysis: - The correct order of acidic strength is: CO2 > SO3 > HClO2 > SiO2 - The incorrect order would be any arrangement that contradicts this conclusion.
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