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Identify the block to which an element w...

Identify the block to which an element with electronic configuration: `[Kr]4d^(10)4f^(14)5s^2 5p^6 5d^1 6s^2` belongs to 

A

s-block

B

p-block

C

d-block

D

f-block

Text Solution

AI Generated Solution

The correct Answer is:
To identify the block to which the element with the electronic configuration `[Kr]4d^(10)4f^(14)5s^2 5p^6 5d^1 6s^2` belongs, we will analyze the outermost electrons in the configuration step by step. ### Step-by-Step Solution: 1. **Identify the outermost shell**: The highest principal quantum number (n) in the given electronic configuration is 6. Therefore, the outermost shell is n=6. 2. **List the electrons in the outermost shell**: The outermost electrons in the configuration are: - 6s² (2 electrons) - 5d¹ (1 electron) 3. **Determine the filled subshells**: The configuration also includes filled subshells: - 4f¹⁴ (14 electrons) - 5s² (2 electrons) - 5p⁶ (6 electrons) - 4d¹⁰ (10 electrons) 4. **Identify the block based on the outermost electrons**: The outermost electrons are in the 6s and 5d subshells. The presence of the 5d subshell indicates that this element is likely in the d-block. However, since we also have electrons in the 4f subshell, we need to consider the f-block as well. 5. **General electronic configuration for f-block elements**: The general electronic configuration for f-block elements is: - (n-2)f¹⁴ (for lanthanides and actinides) - (n-1)d¹⁰ (for transition metals) - ns² (for s-block) In this case, we have: - 4f¹⁴ (n-2, where n=6) - 5d¹ (n-1) - 6s² (ns) 6. **Conclusion**: Since the configuration includes filled f-orbitals (4f¹⁴) and the presence of d and s electrons, we conclude that the element belongs to the f-block of the periodic table. ### Final Answer: The element with the electronic configuration `[Kr]4d^(10)4f^(14)5s^2 5p^6 5d^1 6s^2` belongs to the **f-block** of the periodic table.
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