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Which of the following is/are correct or...

Which of the following is/are correct order of ionization energy? 

A

`Ag gt Cu gt Au`

B

`Sc gt Ygt La`

C

`Pd gt Pt gt N i`

D

`Al le Ga lt B`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of ionization energy for the given elements, we will analyze each set of elements based on their electronic configurations and periodic trends. Here’s a step-by-step breakdown: ### Step 1: Understanding Ionization Energy - **Definition**: Ionization energy is the energy required to remove the outermost electron from an atom in its gaseous state. - **Trend**: Ionization energy generally increases across a period (left to right) and decreases down a group (top to bottom) in the periodic table. ### Step 2: Analyzing the First Set (Cu, Ag, Au) - **Elements**: Copper (Cu), Silver (Ag), Gold (Au) - **Trend**: As we move down the group, the atomic size increases due to additional electron shells, making it easier to remove the outermost electron. - **Conclusion**: The order of ionization energy is Au > Cu > Ag. Thus, this order is incorrect as given (Ag, Cu, Au). ### Step 3: Analyzing the Second Set (Sc, Y, La) - **Elements**: Scandium (Sc), Yttrium (Y), Lanthanum (La) - **Trend**: Similar to the previous set, as we move down the group, the atomic size increases. - **Conclusion**: The order of ionization energy is Sc > Y > La, which is correct. ### Step 4: Analyzing the Third Set (Ni, Pd, Pt) - **Elements**: Nickel (Ni), Palladium (Pd), Platinum (Pt) - **Trend**: Platinum has a filled 4f subshell, leading to less shielding and a smaller size, thus requiring more energy to remove an electron. - **Conclusion**: The order of ionization energy is Pt > Pd > Ni, which is incorrect as given (Pd, Pt, Ni). ### Step 5: Analyzing the Fourth Set (B, Al, Ga) - **Elements**: Boron (B), Aluminium (Al), Gallium (Ga) - **Trend**: Gallium has a filled d subshell which causes less shielding, resulting in a smaller size compared to Aluminium. - **Conclusion**: The order of ionization energy is B > Ga > Al, which is correct. ### Final Conclusion Based on the analysis, the correct orders of ionization energy are: 1. Sc > Y > La (correct) 2. B > Ga > Al (correct) ### Summary of Correct Orders - **Correct Orders**: - Scandium, Yttrium, Lanthanum - Boron, Gallium, Aluminium
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