Home
Class 12
CHEMISTRY
The answer to each of the following is a...

The answer to each of the following is a non-negative integer
Find the number lone pairs in `XeO_2F_2`

Text Solution

AI Generated Solution

The correct Answer is:
To find the number of lone pairs in \( XeO_2F_2 \), we can follow these steps: ### Step 1: Determine the Valence Electrons First, we need to find the total number of valence electrons for \( XeO_2F_2 \): - Xenon (Xe) has 8 valence electrons. - Oxygen (O) has 6 valence electrons, and there are 2 oxygen atoms, contributing \( 2 \times 6 = 12 \) valence electrons. - Fluorine (F) has 7 valence electrons, and there are 2 fluorine atoms, contributing \( 2 \times 7 = 14 \) valence electrons. Adding these together: \[ 8 (Xe) + 12 (O) + 14 (F) = 34 \text{ valence electrons} \] ### Step 2: Draw the Lewis Structure Next, we will draw the Lewis structure for \( XeO_2F_2 \): - Place the central atom \( Xe \) in the center. - Attach the two oxygen atoms and two fluorine atoms to the xenon. - Since oxygen is more electronegative than xenon, it will occupy the axial positions, while fluorine will occupy the equatorial positions. ### Step 3: Count the Bonds Now, we need to account for the bonds formed: - Each \( O \) atom forms a double bond with \( Xe \) (2 bonds per oxygen). - Each \( F \) atom forms a single bond with \( Xe \). This gives us: - 2 double bonds from the oxygen atoms (4 electrons). - 2 single bonds from the fluorine atoms (2 electrons). Total bonding electrons: \[ 4 (from \, O) + 2 (from \, F) = 6 \text{ bonding electrons} \] ### Step 4: Calculate Remaining Electrons Now, we subtract the bonding electrons from the total valence electrons: \[ 34 \text{ total valence electrons} - 6 \text{ bonding electrons} = 28 \text{ remaining electrons} \] ### Step 5: Distribute Remaining Electrons as Lone Pairs Next, we distribute the remaining electrons as lone pairs: - Each fluorine atom will have 6 remaining electrons (3 lone pairs each). - Each oxygen atom will have 4 remaining electrons (2 lone pairs each). - The xenon atom will have the remaining electrons as lone pairs. ### Step 6: Count the Lone Pairs Now, we can count the lone pairs: - Each fluorine contributes 3 lone pairs (2 fluorine atoms contribute \( 3 \times 2 = 6 \) lone pairs). - Each oxygen contributes 2 lone pairs (2 oxygen atoms contribute \( 2 \times 2 = 4 \) lone pairs). - The xenon will have 1 lone pair. Total lone pairs: \[ 6 (from \, F) + 4 (from \, O) + 1 (from \, Xe) = 11 \text{ lone pairs} \] ### Final Answer The total number of lone pairs in \( XeO_2F_2 \) is **11**. ---
Promotional Banner